Acrylic | Polymerization, Synthetic Resin, Monomer

acrylic, a wide spectrum of synthetic resins and fibers, originates from derivatives of acrylic and methacrylic acids. Acrylic acid (CH2=CHCO2H) and methacrylic acid (CH2=C[CH3]CO2H) have been known since the mid-19th century, but it wasn’t until 1901 that their practical potential was recognized, thanks to the research by German chemist Otto Röhm on acrylic ester polymers. By the 1930s, acrylic acid esters were commercially polymerized into polyacrylate resins essential to acrylic paints, while methacrylic acid esters polymerized into polymethyl methacrylate, a clear plastic marketed as Plexiglas and Perspex. E.I. du Pont de Nemours & Company (DuPont) introduced the first successful acrylic fiber, Orlon, in 1950. Both acrylic and modacrylic fibers are synthesized from polyacrylonitrile.

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Beyond these common forms, acrylics also encompass cyanoacrylate resins used in fast-acting adhesives, poly-2-hydroxyethyl methacrylate (polyHEMA) employed in soft contact lenses, polyacrylamide resins serving as flocculants for water clarification, and polyacrylate elastomers utilized in rubber products.

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