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The Introduction of Silane Crosslinking Agent

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Ingrid
Apr. 29, 2024
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The Introduction of Silane Crosslinking Agent

refers to a silane containing two or more silicon functional groups. It can act as an in-line molecular bridge, so that multiple linear molecules or lightly branched macromolecules and polymers can be bonded to each other to form a three-dimensional network structure, which promotes or mediates formation of a bond or ionic bond between polymer molecular chains.

Crosslinking agent is the core part of one-component room temperature vulcanized silicone rubber, which is the basis for determining the cross-linking mechanism and classification of products.

According to the different condensation reaction products, the one-component room temperature vulcanization silicone rubber can be divided into different types such as deacidification type, deketoxime type, dealcoholization type, deamination type, deamidation type, and acetone removal type. It is a general-purpose product for mass production.

Taking the

In general, are different from silane coupling agents, but there are exceptions. The aniline methyl triethoxy silane   represented by α series silane coupling agent has been widely used in the one-component dealcoholized room temperature vulcanized silicone rubber.

Common are:
Dealcoholic silane: alkyl triethoxy, methyl trimethoxy
Deacidified silane: triacetoxy, propyl triacetoxysilane
Deketoxime silane: vinyl tributol sulfonyl silane, methyl tributol ketone silane
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refers to a silane containing two or more silicon functional groups. It can act as an in-line molecular bridge, so that multiple linear molecules or lightly branched macromolecules and polymers can be bonded to each other to form a three-dimensional network structure, which promotes or mediates formation of a bond or ionic bond between polymer molecular chains.Crosslinking agent is the core part of one-component room temperature vulcanized silicone rubber, which is the basis for determining the cross-linking mechanism and classification of products.According to the different condensation reaction products, the one-component room temperature vulcanization silicone rubber can be divided into different types such as deacidification type, deketoxime type, dealcoholization type, deamination type, deamidation type, and acetone removal type. It is a general-purpose product for mass production.Taking the methyltriacetoxysilane crosslinking agent as an example, since the condensation reaction product is acetic acid, it is called a deacetic acid type room temperature vulcanized silicone rubber.In general,are different from silane coupling agents, but there are exceptions. The aniline methyl triethoxy silane represented by α series silane coupling agent has been widely used in the one-component dealcoholized room temperature vulcanized silicone rubber.Commonare:Dealcoholic silane: alkyl triethoxy, methyl trimethoxyDeacidified silane: triacetoxy, propyl triacetoxysilaneDeketoxime silane: vinyl tributol sulfonyl silane, methyl tributol ketone silane

Understanding the effect of silane crosslinking reaction on ...

  1. Baker W, Scott C, Hu G (2001) Reactive polymer blending. Hanser, Munich

  2. Folkes M, Hope P (1993) Polymer blends and alloys. Chapman & Hall, London

  3. Sailer C, Handge UA (2007) Melt viscosity, elasticity, and morphology of reactively compatibilized polyamide 6/styrene–acrylonitrile blends in shear and elongation. Macromolecules 40:2019–2028

  4. Bartczak Z, Argon AS, Cohen RE, Weinbergu M (1999) Toughness mechanism in semi-crystalline polymer blends: I. High-density polyethylene toughened with rubbers. Polymer 40:2331–2346

  5. Holz N, Goizueta GS, Capiati N (2010) Linear low-density polyethylene addition to polypropylene/elastomer blends: phase structure and impact properties. Polym Eng Sci 36:2765–2770

  6. Macaubas PHP, Demarquette NR (2001) Morphologies and interfacial tensions of immiscible polypropylene/polystyrene blends modified with triblock copolymers. Polymer 42:2543–2554

  7. Liu GY, Qiu GX (2013) Study on the mechanical and morphological properties of toughened polypropylene blends for automobile bumpers. Polym Bull 70:849–857

  8. Mazidi MM, Aghjeh MKR (2015) Effects of blend composition and compatibilization on the melt rheology and phase morphology of binary and ternary PP/PA6/EPDM blends. Polym Bull 72:1975–2000

  9. Wang FF, Du HN, Liu H, Zhang Y, Zhang XW, Zhang J (2015) The synergistic effects of β-nucleating agent and ethylene-octene copolymer on toughening isotactic polypropylene. Polym Test 45:1–11

  10. Sirisinha K, Boonkongkaew M, Kositchaiyong S (2010) The effect of silane carriers on silane grafting of high-density polyethylene and properties of crosslinked products. Polym Test 29:958–965

  11. Sirisinha K, Chimdist S (2008) Silane-crosslinked ethylene–octene copolymer blends: thermal aging and crystallization study. J Appl Polym Sci 109:2522–2528

  12. Jung ST, Kim DY, Kim HB, Jeun JP, Oh SH, Lee BJ, Kang PH (2013) Enhanced solvent resistance of acrylonitrile–butadiene rubber by electron beam irradiation. J Ind Eng Chem 19:566–570

  13. Yuan B, Chen X, He BB (2008) Studies on rheology and morphology of POE/PP thermoplastic elastomer dynamically crosslinked by peroxide. J Vinyl Addit Technol 14:45–54

  14. Baek BK, La YH, Na WJ, Lee SH, Hong SM, Han H, Lee YW, Nam GJ, Koo CM (2016) A kinetic study on the supercritical decrosslinking reaction of silane-crosslinked polyethylene in a continuous process. Polym Degrad Stabil 126:75–80

  15. Garnier L, Duquesne S, Casetta M, Lewandowski M, Bourbigot S (2010) Melt spinning of silane–water cross-linked polyethylene–octene through a reactive extrusion process. React Funct Polym 70:775–783

  16. Zhang GQ, Wang GL, Zhang J, Wei P, Jiang PK (2006) Performance evaluation of silane crosslinking of metallocene-based polyethylene–octene elastomer. J Appl Polym Sci 102:5057–5061

  17. Ramar P, Alagar M (2004) Studies on grafting of tris(2-methoxyethoxy)vinylsilane onto ethylene-propylene-diene terpolymer. Polym Adv Technol 15:377–381

  18. Kamphunthong W, Sirisinha K (2008) Structure development and viscoelastic properties in silane-crosslinked ethylene–octene copolymer. J Appl Polym Sci 109:2347–2353

  19. Sen SK, Mukherjee B, Bhattacharyya AS, De PP, Bhowmick AK (1992) Kinetics of silane grafting and moisture crosslinking of polyethylene and ethylene propylene rubber. J Appl Polym Sci 44:1153–1164

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  20. Shieh YT, Chuang HC (2001) DSC and DMA studies on silane-grafted and water-crosslinked LDPE/LLDPE blends. J Appl Polym Sci 81:1808–1816

  21. Nordin R, Ismail H, Ahmad Z, Rashid A (2012) Performance improvement of (linear low-density polyethylene)/poly(vinyl alcohol) blends by in situ silane crosslinking. J Vinyl Addit Technol 18:120–128

  22. Wang ZZ, Wu XS, Gui Z, Hu Y, Fan WC (2005) Thermal and crystallization behavior of silane-crosslinked polypropylene. Polym Int 54:442–447

  23. Zhou S, Wang ZZ, Hu Y (2009) Melt grafting of vinyltrimethoxysilane and water crosslinking of polypropylene/ethylene-propylene diene terpolymer blends. J Polym Res 16:173–181

  24. Xu CH, Fang LM, Chen YK (2014) In situ reactive compatibilized polypropylene/nitrile butadiene rubber blends by zinc dimethacrylate: preparation, structure, and properties. Polym Eng Sci 54:2321–2331

  25. Mali M, Kadam P, Mhaske S (2017) Preparation and characterization of vinyltrimethoxysilane and dicumyl peroxide–cured (ethylene propylene diene monomer)/polypropylene thermoplastic vulcanizates. J Vinyl Addit Technol 23:312–320

  26. Bailly M, Kontopoulou M (2009) Preparation and characterization of thermoplastic olefin/nanosilica composites using a silane-grafted polypropylene matrix. Polymer 50:2472–2480

  27. An YJ, Zhang ZJ, Bi WG, Wang YH, Tang T (2008) Characterization of high melt strength polypropylene synthesized via silane grafting initiated by in situ heat induction reaction. J Appl Polym Sci 110:3727–3732

  28. Zhou HM, Ying JR, Liu F, Xie XL, Li DQ (2010) Non-isothermal crystallization behavior and kinetics of isotactic polypropylene/ethylene-octene blends. Part I: crystallization behavior. Polym Test 29:640–647

  29. Ying JR, Liu SP, Guo F, Zhou XP, Xie XL (2008) Non-isothermal crystallization and crystalline structure of PP/POE blends. J Therm Anal Calorim 91:723–731

  30. Wang JF, Guo JW, Li CH, Yang S, Wu H, Guo SY (2014) Crystallization kinetics behavior, molecular interaction, and impact-induced morphological evolution of polypropylene/poly(ethylene-co-octene) blends: insight into toughening mechanism. J Polym Res 21:618

  31. Liu GY, Qiu GX (2013) Study on the mechanical and morphological properties of toughened polypropylene blends for automobile bumpers. Polym Bull 70:849–857

  32. Wang WJ, Song XL, Wei JM, Cao SK, Cao YX, Chen JZ, Wang JW (2015) A rheological method for the determination of “super toughness point” of polymer blends: a blend system of nylon1212 with maleated poly(ethylene-octene). J Rheol 59:1431–1447

  33. Wang WJ, Li CH, Cao YX, Chen JZ, Wang JW (2012) Rheological characteristics and morphologies of styrene–butadiene–maleic anhydride block copolymers. J Appl Polym Sci 123:3234–3241

  34. Wang WJ, Cao YX, Wang JW, Zheng Q (2009) Rheological characterization and morphology of nylon 1212/functional elastomer blends. J Appl Polym Sci 112:953–962

  35. Martin JE, Adolf D (1991) The sol–gel transition in chemical gels. Annu Rev Phys Chem 42:311–339

  36. Dumitraş M, Friedrich C (2004) Network formation and elasticity evolution in dibenzylidene sorbitol/poly(propylene oxide) physical gels. J Rheol 48:1135–1146

  37. Power DJ, Rodd AB, Paterson L, Boger DV (1998) Gel transition studies on nonideal polymer networks using small amplitude oscillatory rheometry. J Rheol 42:1021–1037

  38. Chambon F, Winter HH (1987) Linear viscoelasticity at the gel point of a crosslinking PDMS with imbalanced stoichiometry. J Rheol 31:683–697

  39. Winter HH, Chambon F (1986) Analysis of linear viscoelasticity of a crosslinking polymer at the gel point. J Rheol 30:367–382


  40. High Purity 4-Amino-3, 5-Dichloroacetophenone Powder ...
    Know Your Non-Metallics: Nitrile Rubber

    Ismail H, Supri Yusof AMM (2004) Blend of waste poly(vinylchloride) (PVCw)/acrylonitrile butadiene-rubber (NBR): the effect of maleic anhydride (MAH). Polym Test 23:675–683

    Additional reading:
    Hydroxypropyl methylcellulose, a viscous soluble fiber ...

    The Introduction of Silane Crosslinking AgentSilane Crosslinking Agent

    refers to a silane containing two or more silicon functional groups. It can act as an in-line molecular bridge, so that multiple linear molecules or lightly branched macromolecules and polymers can be bonded to each other to form a three-dimensional network structure, which promotes or mediates formation of a bond or ionic bond between polymer molecular chains.

    Crosslinking agent is the core part of one-component room temperature vulcanized silicone rubber, which is the basis for determining the cross-linking mechanism and classification of products.

    According to the different condensation reaction products, the one-component room temperature vulcanization silicone rubber can be divided into different types such as deacidification type, deketoxime type, dealcoholization type, deamination type, deamidation type, and acetone removal type. It is a general-purpose product for mass production.

    Taking the

    In general, are different from silane coupling agents, but there are exceptions. The aniline methyl triethoxy silane   represented by α series silane coupling agent has been widely used in the one-component dealcoholized room temperature vulcanized silicone rubber.

    Common are:
    Dealcoholic silane: alkyl triethoxy, methyl trimethoxy
    Deacidified silane: triacetoxy, propyl triacetoxysilane
    Deketoxime silane: vinyl tributol sulfonyl silane, methyl tributol ketone silane
    Enable GingerCannot connect to Ginger Check your internet connection
    or reload the browserDisable in this text fieldRephraseRephrase current sentence

    Edit in Ginger

    refers to a silane containing two or more silicon functional groups. It can act as an in-line molecular bridge, so that multiple linear molecules or lightly branched macromolecules and polymers can be bonded to each other to form a three-dimensional network structure, which promotes or mediates formation of a bond or ionic bond between polymer molecular chains.Crosslinking agent is the core part of one-component room temperature vulcanized silicone rubber, which is the basis for determining the cross-linking mechanism and classification of products.According to the different condensation reaction products, the one-component room temperature vulcanization silicone rubber can be divided into different types such as deacidification type, deketoxime type, dealcoholization type, deamination type, deamidation type, and acetone removal type. It is a general-purpose product for mass production.Taking the methyltriacetoxysilane crosslinking agent as an example, since the condensation reaction product is acetic acid, it is called a deacetic acid type room temperature vulcanized silicone rubber.In general,are different from silane coupling agents, but there are exceptions. The aniline methyl triethoxy silane represented by α series silane coupling agent has been widely used in the one-component dealcoholized room temperature vulcanized silicone rubber.Commonare:Dealcoholic silane: alkyl triethoxy, methyl trimethoxyDeacidified silane: triacetoxy, propyl triacetoxysilaneDeketoxime silane: vinyl tributol sulfonyl silane, methyl tributol ketone silane

    Understanding the effect of silane crosslinking reaction on ...

    1. Baker W, Scott C, Hu G (2001) Reactive polymer blending. Hanser, Munich

    2. Folkes M, Hope P (1993) Polymer blends and alloys. Chapman & Hall, London

    3. Sailer C, Handge UA (2007) Melt viscosity, elasticity, and morphology of reactively compatibilized polyamide 6/styrene–acrylonitrile blends in shear and elongation. Macromolecules 40:2019–2028

    4. Bartczak Z, Argon AS, Cohen RE, Weinbergu M (1999) Toughness mechanism in semi-crystalline polymer blends: I. High-density polyethylene toughened with rubbers. Polymer 40:2331–2346

    5. Holz N, Goizueta GS, Capiati N (2010) Linear low-density polyethylene addition to polypropylene/elastomer blends: phase structure and impact properties. Polym Eng Sci 36:2765–2770

    6. Macaubas PHP, Demarquette NR (2001) Morphologies and interfacial tensions of immiscible polypropylene/polystyrene blends modified with triblock copolymers. Polymer 42:2543–2554

    7. Liu GY, Qiu GX (2013) Study on the mechanical and morphological properties of toughened polypropylene blends for automobile bumpers. Polym Bull 70:849–857

    8. Mazidi MM, Aghjeh MKR (2015) Effects of blend composition and compatibilization on the melt rheology and phase morphology of binary and ternary PP/PA6/EPDM blends. Polym Bull 72:1975–2000

    9. Wang FF, Du HN, Liu H, Zhang Y, Zhang XW, Zhang J (2015) The synergistic effects of β-nucleating agent and ethylene-octene copolymer on toughening isotactic polypropylene. Polym Test 45:1–11

    10. Sirisinha K, Boonkongkaew M, Kositchaiyong S (2010) The effect of silane carriers on silane grafting of high-density polyethylene and properties of crosslinked products. Polym Test 29:958–965

    11. Sirisinha K, Chimdist S (2008) Silane-crosslinked ethylene–octene copolymer blends: thermal aging and crystallization study. J Appl Polym Sci 109:2522–2528

    12. Jung ST, Kim DY, Kim HB, Jeun JP, Oh SH, Lee BJ, Kang PH (2013) Enhanced solvent resistance of acrylonitrile–butadiene rubber by electron beam irradiation. J Ind Eng Chem 19:566–570

    13. Yuan B, Chen X, He BB (2008) Studies on rheology and morphology of POE/PP thermoplastic elastomer dynamically crosslinked by peroxide. J Vinyl Addit Technol 14:45–54

    14. Baek BK, La YH, Na WJ, Lee SH, Hong SM, Han H, Lee YW, Nam GJ, Koo CM (2016) A kinetic study on the supercritical decrosslinking reaction of silane-crosslinked polyethylene in a continuous process. Polym Degrad Stabil 126:75–80

    15. Garnier L, Duquesne S, Casetta M, Lewandowski M, Bourbigot S (2010) Melt spinning of silane–water cross-linked polyethylene–octene through a reactive extrusion process. React Funct Polym 70:775–783

    16. Zhang GQ, Wang GL, Zhang J, Wei P, Jiang PK (2006) Performance evaluation of silane crosslinking of metallocene-based polyethylene–octene elastomer. J Appl Polym Sci 102:5057–5061

    17. Ramar P, Alagar M (2004) Studies on grafting of tris(2-methoxyethoxy)vinylsilane onto ethylene-propylene-diene terpolymer. Polym Adv Technol 15:377–381

    18. Kamphunthong W, Sirisinha K (2008) Structure development and viscoelastic properties in silane-crosslinked ethylene–octene copolymer. J Appl Polym Sci 109:2347–2353

    19. Sen SK, Mukherjee B, Bhattacharyya AS, De PP, Bhowmick AK (1992) Kinetics of silane grafting and moisture crosslinking of polyethylene and ethylene propylene rubber. J Appl Polym Sci 44:1153–1164

    20. Shieh YT, Chuang HC (2001) DSC and DMA studies on silane-grafted and water-crosslinked LDPE/LLDPE blends. J Appl Polym Sci 81:1808–1816

    21. Nordin R, Ismail H, Ahmad Z, Rashid A (2012) Performance improvement of (linear low-density polyethylene)/poly(vinyl alcohol) blends by in situ silane crosslinking. J Vinyl Addit Technol 18:120–128

    22. Wang ZZ, Wu XS, Gui Z, Hu Y, Fan WC (2005) Thermal and crystallization behavior of silane-crosslinked polypropylene. Polym Int 54:442–447

    23. Zhou S, Wang ZZ, Hu Y (2009) Melt grafting of vinyltrimethoxysilane and water crosslinking of polypropylene/ethylene-propylene diene terpolymer blends. J Polym Res 16:173–181

    24. Xu CH, Fang LM, Chen YK (2014) In situ reactive compatibilized polypropylene/nitrile butadiene rubber blends by zinc dimethacrylate: preparation, structure, and properties. Polym Eng Sci 54:2321–2331

    25. Mali M, Kadam P, Mhaske S (2017) Preparation and characterization of vinyltrimethoxysilane and dicumyl peroxide–cured (ethylene propylene diene monomer)/polypropylene thermoplastic vulcanizates. J Vinyl Addit Technol 23:312–320

    26. Bailly M, Kontopoulou M (2009) Preparation and characterization of thermoplastic olefin/nanosilica composites using a silane-grafted polypropylene matrix. Polymer 50:2472–2480

    27. An YJ, Zhang ZJ, Bi WG, Wang YH, Tang T (2008) Characterization of high melt strength polypropylene synthesized via silane grafting initiated by in situ heat induction reaction. J Appl Polym Sci 110:3727–3732

    28. Zhou HM, Ying JR, Liu F, Xie XL, Li DQ (2010) Non-isothermal crystallization behavior and kinetics of isotactic polypropylene/ethylene-octene blends. Part I: crystallization behavior. Polym Test 29:640–647

    29. Ying JR, Liu SP, Guo F, Zhou XP, Xie XL (2008) Non-isothermal crystallization and crystalline structure of PP/POE blends. J Therm Anal Calorim 91:723–731

    30. Wang JF, Guo JW, Li CH, Yang S, Wu H, Guo SY (2014) Crystallization kinetics behavior, molecular interaction, and impact-induced morphological evolution of polypropylene/poly(ethylene-co-octene) blends: insight into toughening mechanism. J Polym Res 21:618

    31. Liu GY, Qiu GX (2013) Study on the mechanical and morphological properties of toughened polypropylene blends for automobile bumpers. Polym Bull 70:849–857

    32. Wang WJ, Song XL, Wei JM, Cao SK, Cao YX, Chen JZ, Wang JW (2015) A rheological method for the determination of “super toughness point” of polymer blends: a blend system of nylon1212 with maleated poly(ethylene-octene). J Rheol 59:1431–1447

    33. Wang WJ, Li CH, Cao YX, Chen JZ, Wang JW (2012) Rheological characteristics and morphologies of styrene–butadiene–maleic anhydride block copolymers. J Appl Polym Sci 123:3234–3241

    34. Wang WJ, Cao YX, Wang JW, Zheng Q (2009) Rheological characterization and morphology of nylon 1212/functional elastomer blends. J Appl Polym Sci 112:953–962

    35. Martin JE, Adolf D (1991) The sol–gel transition in chemical gels. Annu Rev Phys Chem 42:311–339

    36. Dumitraş M, Friedrich C (2004) Network formation and elasticity evolution in dibenzylidene sorbitol/poly(propylene oxide) physical gels. J Rheol 48:1135–1146

    37. Power DJ, Rodd AB, Paterson L, Boger DV (1998) Gel transition studies on nonideal polymer networks using small amplitude oscillatory rheometry. J Rheol 42:1021–1037

    38. Chambon F, Winter HH (1987) Linear viscoelasticity at the gel point of a crosslinking PDMS with imbalanced stoichiometry. J Rheol 31:683–697

    39. Winter HH, Chambon F (1986) Analysis of linear viscoelasticity of a crosslinking polymer at the gel point. J Rheol 30:367–382

    40. Ismail H, Supri Yusof AMM (2004) Blend of waste poly(vinylchloride) (PVCw)/acrylonitrile butadiene-rubber (NBR): the effect of maleic anhydride (MAH). Polym Test 23:675–683

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